大冶湖流域不同土地利用土壤铜分布特征及成因

Distribution Characteristics and Genetic Formation of Copper in Soils with Different Land Use Types in Daye Lake Basin

  • 摘要:
    目的 明确大冶湖流域不同土地利用土壤重金属铜(Cu)分布特征及其差异,为大冶湖流域不同土地利用土壤Cu污染防控、土地资源合理配置和可持续利用提供科学依据。
    方法 运用普通克里金插值和单因素方差分析,对大冶湖流域重金属Cu的空间分布特征及不同土地利用间的差异进行分析。
    结果 ①实测地类(除水域及水利设施用地)土壤Cu含量均超过湖北省土壤背景值,以公共管理与公共服务用地最高,是湖北省土壤背景值的16.74倍;耕地、园地、林地、草地、公共管理与公共服务用地、水域及水利设施用地和其他土地等7种地类的土壤Cu含量均超过中国土壤背景值,并且公共管理与公共服务用地和其他6种地类的土壤Cu含量存在显著差异(P < 0.05)。②插值后流域内各地类重金属Cu的平均值均未超过国家土壤环境质量标准,但是都超过中国土壤背景值;除特殊用地,其余11种地类的Cu含量均超过湖北省和世界土壤背景值,商服用地和工矿仓储用地较高;同时,特殊用地与园地之外的其他10种地类Cu含量差异显著(P < 0.05);园地重金属Cu含量与其他4种地类(草地、商服用地、工矿仓储用地和交通运输用地)之间差异显著(P < 0.05)。
    结论 大冶湖流域重金属Cu的高值区主要分布在北部、中部及东南部,最大值分别为1146.45 mg kg−1、1822 mg kg−1和1689 mg kg−1。大冶湖流域土壤Cu污染具有显著的空间分异性, 工矿活动是其主要成因。

     

    Abstract:
    Objective The aims were to explore the distribution characteristics and differences of soil heavy metal in different land use types in Daye Lake Basin, in order to provide certain scientific basis and decision-making support for the prevention and control of copper (Cu) contamination in soils, the rational utilization and sustainable use of land resources.
    Method The spatial distribution characteristics of Cu and its differences in soils with different land use types in Daye Lake Basin were analyzed using ordinary kriging interpolation and one-way analysis of variance (ANOVA).
    Result ① The Cu content of the measured land use types (except for the waters and water conservancy facility land) exceeded the soil background value of Hubei Province, and was the highest in public management and public service land, which was 16.74 times higher than the soil background value of Hubei Province. The Cu contents of seven land categories (e.g., arable land, orchard land, forest land, grassland, public management and public service land, waters and water conservancy facility land, and other land) exceeded the limit of Chinese soil's background value. Furthermore, the difference of Cu contents between public management and public service land and the other six land use types were significant (P<0.05). (2) The mean values of interpolated heavy metal Cu contents for each land use type did not exceed the threshold of China Soil Environmental Quality Standards, but they all exceeded the limit of Chinese soil’s background values. The Cu content of all the other 11 land use types (except for special land) exceeded the soil background values of Hubei Province and the whole world, other than that, commercial and services land and industrial and mining warehouse land were relatively higher than other land use types. Meanwhile, the difference of heavy metal Cu contents between special land and the other 10 land use types were significant (P < 0.05), but not for orchard land. Soil Cu content of orchard land differed significantly (P<0.05) from that of the other four land types (grassland, commercial and services land, industrial and mining warehouse land, and transportation land).
    Conclusion The maximum values of soil Cu content were mainly located in the northern, central and southeastern area of Daye Lake Basin, and their values were 1146.45 mg kg−1, 1822 mg kg−1 and 1689 mg kg−1, respectively. Heavy metal pollution in Daye Lake basin exhibits significant spatial differentiation which is mainly caused by industrial and mining activities.

     

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