黄石市绿地土壤重金属污染风险评价及来源解析

Risk Assessment and Source Analysis of Heavy Metal Pollution in Green Space Soil in Huangshi city

  • 摘要:
      目的  城市绿地土壤健康问题日益受到人们的广泛关注。掌握黄石市绿地土壤重金属污染情况,为当地及同类矿冶城市生态建设与转型发展提供技术支撑。
      方法  按照多点混合法选择黄石市道路绿地布设采样点,共采集土壤样品48个,测定其多种金属元素含量。使用地累积指数法、潜在生态危害指数法以及多元统计分析法对其进行污染评价;使用ArcGis10.2进行重金属分布可视化分析;利用相关性分析与主成分分析法对各重金属元素进行来源解析。
      结果  土壤铅(Pb)、锌(Zn)、铬(Cr)、砷(As)、镉(Cd)、铜(Cu)的平均含量分别为200.12、424.88、109.96、56.74、4.02、376.81 mg kg−1,分别超出湖北省土壤背景值7.49、5.08、1.28、4.61、23.67、12.27倍,除Cr均未超出背景值外,各金属超出背景值样点占总体的比率分别为Cu 100%、Pb 97.92%、Zn 97.92%、As 93.75%、Cd 100%;地累积指数评价结果为53.06% ~ 87.08%样点处于中重度污染水平,89.58%样点的综合潜在生态危害指数大于150。
      结论  土壤Cr含量空间分布较为均匀,但仍存在高值区,高值区位于西塞山区某大型冶钢企业附近。土壤Pb、Zn、As、Cu、Cd含量差异大,高值区均位于黄石港区,极高值点均位于下陆区某大型有色金属冶炼厂附近;6种重金属的地累积指数大小、即污染程度依次为:Cd > Pb > Cu > Zn > As > Cr,潜在生态危害指数为:Cd > Cu > As > Pb > Zn > Cr,可见Cd是该研究区域内最主要的重金属污染元素;多元统计分析表明Pb、Zn、As、Cd、Cu来源于人为源,与有色金属冶炼、交通有关,Cr主要来源于岩石的风化和土壤母质等。

     

    Abstract:
      Objective  The problem of soil health in urban green space has been widely concerned by people. The purpose of this study is to grasp the heavy metal pollution of green space soil in Huangshi City, Hubei Province, and to provide technical support for the ecological construction and transformation development of such mining and metallurgical cities.
      Method  According to the multi-point mixing method, sampling points were selected for road green space layout in Huangshi City. A total of 48 soil samples were collected to determine the contents of various metal elements. The geo-accumulation index method, the potential ecological hazard index method and multivariate statistical analysis were used to evaluate the pollution. ArcGis10.2 was used to visualize the distribution of heavy metals, and the correlation analysis and principal component analysis were used to analyze the source of each heavy metal element.
      Result  The results showed that the average contents of Pb, Zn, Cr, As, Cd and Cu were 200.12, 424.88, 109.96, 56.74, 4.02 and 376.81 mg kg−1. They exceed the background value in Hubei Province by 7.49, 5.08, 1.28, 4.61, 23.67 and 12.27 times, respectively. Except for Cr, the percentages of points exceeding the background value to the total were: Cu 100%, Pb 97.92%, Zn 97.92%, As 93.75% and Cd 100%. The evaluation of the geo-accumulative index showed that 53.06%-87.08% samples are at a moderate to severe pollution level, and the comprehensive potential ecological hazard index of 89.58% samples was greater than 150.
      Conclusion  The distribution of Cr is relatively uniform, but there are still high value areas, which are located near a large steel smelting enterprise in Xisai Mountains. The distributions of Pb, Zn, As, Cu and Cd contents are quite different. High-value areas are all located in Huangshi Port area, and extremely high-value points are located near a large non-ferrous metal smelting plant in Xialu District. The geo-accumulation index indicates that the pollution degree of the six heavy metals is: Cd > Pb > Cu > Zn > As > Cr; the potential ecological hazard index is: Cd > Cu > As > Pb > Zn > Cr. Cd is the most important pollution element in the area. Multivariate statistical analysis shows that Pb, Zn, As, Cd, and Cu are anthropogenic sources and are related to non-ferrous metal smelting and transportation. Cr mainly comes from weathering of rocks and soil parent materials.

     

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