松嫩平原产油区农田土壤重金属含量及污染风险评价

Heavy Metal Contents and Pollution Risk Assessment in Farmland Soil of the Oil Producing Areas on the Songnen Plain

  • 摘要:
      目的  为探明松嫩平原石油开采及石化工业活动区周边农田土壤重金属污染分布及风险状况。
      方法  在大庆市让胡路区选择代表性农田采集96份土壤样品,测定重金属(Cd、Hg、Ni、Pb、Cu、Zn、Cr、As)含量;在利用地统计学克里金插值法分析重金属含量空间分布特征的基础上,采用地积累指数法和潜在生态危害指数法对该地区农田土壤重金属污染状况及其生态风险进行评价。
      结果  该区土壤中Cd和Ni的含量分别为土壤背景值的1.39倍和1.27倍。在对各样点Pb、Zn、Cu和Cr 4种元素含量分析中,均出现不同程度的高于土壤背景值的样点。重金属Cd的地积累指数平均值为0.11,达到轻度~中度污染水平。研究区土壤重金属潜在生态危害风险指数(RI)平均值为84.84,从大到小为Cd > Hg > Ni > As > Pb > Cu > Zn > Cr,其中Cd的RI值最大为190.23,达到中等生态危害范围。研究区农田土壤重金属含量在空间分布上表现为:Cd、Zn和Pb含量高值区出现在中部地区,其它重金属元素含量高值区分布比较零散。
      结论  研究区域内,8种重金属含量的平均值均低于风险筛选值,Cd和Ni两种重金属平均含量超出了背景值,从地积累指数来看,Cd污染等级为1级,其它7种元素均处于无污染水平。从潜在生态风险分析可知,该区域污染程度属于轻度生态危害范围。

     

    Abstract:
      Objective  The purpose is to find out the distribution and risks of heavy metal pollution in farmland soils around the oil exploitation and petrochemical industrial areas of Songnen Plain.
      Method  Taking the farmland soil in Ranghulu District of Daqing as the research object, 96 soil samples were collected to analyze the contents of heavy metals (Cd, Hg, Ni, Pb, Cu, Zn, Cr and As). The Kriging interpolation was applied to analyze the spatial distribution of heavy metals using geostatistics module software. With adoption of geo-accumulation index method and potential ecological hazard index method, an assessment was carried out to research the pollution of farmland soil in this area.
      Result  The results showed that the contents of Cd and Ni were 1.39 and 1.27 times of the soil background value. The contents of Pb, Zn, Cu and Cr exceeded the soil background value to different extent in some sample points. The mean geo-accumulation index of Cd was 0.11, indicating mild ~ medium pollution. The mean potential ecological risk index (RI) of heavy metals in soil was 84.84 in the researched area, and the RI followed the sequence of Cd > Hg > Ni > As > Pb > Cu > Zn > Cr. The RI value of Cd was the largest at 190.23 among them, indicating the medium ecological hazard. In terms of spatial distribution of heavy metals in farmland soil in the researched area, Cd, Zn and Pb were concentrated in the central area, while the concentration of the rest heavy metals was relatively scattered.
      Conclusion  The mean content of the 8 heavy metals is lower than the risk screening value, while that of both Cd and Ni exceeds the background value. For the geo-accumulation index, Cd pollution reaches Level-I and the rest 7 elements are at non-pollution level. It can be learned from the potential ecological risk analysis that the pollution is in the mild ecological hazard in this area.

     

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