开封市某高校校园地表灰尘重金属分布特征及生态风险评估

Distribution Characteristics and Ecological Risk Assessment of Heavy Metals in Surface Dust from a University Campus in Kaifeng, China

  • 摘要:
      目的  高校校园地表灰尘重金属污染关系到师生健康,探究其地表灰尘重金属环境风险,可为高校校园管理提供数据支持。
      方法  采集开封市某高校校园内外地表灰尘52个样品,测定样品中重金属镉(Cd)、铬(Cr)、铜(Cu)、镍(Ni)、铅(Pb)和锌(Zn)的含量,使用地积累指数法和潜在生态风险指数法分析重金属的污染程度和生态风险。
      结果   高校地表灰尘重金属Cd、Cr、Cu、Ni、Pb和Zn平均含量分别为1.05、88.36、47.04、29.76、68.72和328.87 mg kg−1,其中Cd和Zn含量分别为当地灰尘背景值的3.49倍和4.26倍。地积累指数分析表明,地表灰尘重金属污染指数平均值由高到低依次为Zn > Cd > Pb > Cu > Cr > Ni,其中Zn与Cd处于偏中度污染,Pb,Cu和Cr处于轻度污染,Ni处于无污染状态。潜在生态风险评价表明,高校地表灰尘中6种重金属综合潜在生态风险指数为144.53,属于“轻微”生态风险等级,其中Cd是该高校地表灰尘中最主要的生态风险影响因子。正定矩阵因子分析法(PMF)表明,Cr和Ni主要来源于成土母质,Cd、Cu、Pb和Zn主要来源于交通、工业污染、大气沉降等复合源。
      结论  该高校道路地表灰尘重金属处于轻度到中度污染水平之间,重金属Cd是高校地表灰尘中最主要的污染因子,这些数据可为今后高校校园管理和环境规划提供一些参考。

     

    Abstract:
      Objective  Heavy metal pollution of surface dust in the university campus is an important issue for the safety of teachers and students. The environmental concentration and risk of heavy metals in the surface dust from the university campus were investigated in order to provide a reference for the health of teachers and students and campus management.
      Method  Surface dust samples were collected from the university campus in Kaifeng city. The concentrations of Cd, Cr, Cu, Ni, Pb and Zn were measured by standard methods. The pollution degree of heavy metals pollution was calculated by the geo-accumulation index method and the ecological risk of heavy metals was assessed by the potential ecological risk index method.
      Result  The results showed that the average concentrations of Cd, Cr, Cu, Ni, Pb, and Zn were 1.05, 88.36, 47.04, 29.76, 68.72 and 328.87 mg kg−1, respectively, of which the contents of Cd and Zn were 3.49 and 4.26 times of the background value of dust in Kaifeng, respectively. Geo-accumulated index analysis showed that the order of pollution index of heavy metals from the high to low was Zn, Cd, Pb, Cu, Cr, Ni, and Zn and Cd had been shown the moderate pollution, Pb, Cu and Cr were the light pollution, while Ni was no enrichment. The results of the potential ecological risk assessment indicated that the order of the average ecological risk of heavy metals in surface dust from the high to low was Cd, Pb, Cu, Ni, Zn, and Cr. The average comprehensive potential ecological risk index (RI) value was 144.53, which belongs to a slight level. Moreover, the main factor of potential ecological risks was attributed to cadmium in surface dust. The results of positive definite matrix factor analysis (PMF) showed that, Cr and Ni mainly came from natural parent materials, Cd, Cu, Pb and Zn mainly were derived from the source of vehicle emissions, industrial pollution and atmospheric deposition sources.
      Conclusion  The accumulation degree of heavy metals in the surface dust of the university campus is in the range of mild to moderate pollution level, and the Cd element is the most important pollution factor. Our results can provide some insights into the heavy metal pollution control in the university campus management and environmental planning.

     

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