贵阳市主城区绿化带土壤多环芳烃污染特征及健康风险评估

Pollution Characteristics and Human Health Risk Assessment of Polycyclic Aromatic Hydrocarbons (PAHs) in Soil of Green Belt in Main Urban Area of Guiyang City

  • 摘要:
    目的 为贵阳市主城区绿化带土壤中16种多环芳烃(Polycyclic aromatic hydrocarbons,PAHs)环境评价与健康风险评估提供参考数据。
    方法 采用气相色谱三重四级杆质谱仪,选择离子模式对贵阳市6个主城区,共计30个绿化带土壤样品进行PAHs含量检测。
    结果 主城区绿化带土壤中PAHs主要源于外源性污染。其中6种PAHs符合国家建设用地风险筛选值标准,但土壤整体受到污染程度比例较高;夜市功能区中,因烧烤与油炸2种主要方式产生大量PAHs,使邻近绿化带土壤富集量明显高于其他功能区。特征比值法评价结果显示,燃煤等生物质燃料燃烧在家居小区的排放贡献源中占有一定比例,学校功能区主要排放贡献源为机动车排放的石油燃烧尾气。评估结果表明,其健康风险以皮肤接触致癌风险为主。
    结论 贵阳市主城区绿化带土壤受PAHs污染比例较高,且4 ~ 6环高分子量PAHs含量均高于2 ~ 3环低分子量PAHs。土壤中PAHs对儿童与成人均有潜在致癌风险。因此,应采取相应措施,减少污染源,降低主城区绿化带土壤污染程度。

     

    Abstract:
    Objective The aims were to provide reference data for the environmental assessment and health risk assessment of 16 Polycyclic aromatic hydrocarbons (PAHs) in the soil of the green belt in Guiyang City.
    Methods The content of polycyclic aromatic hydrocarbons (PAHs) in soil samples of 30 green belts in 6 main urban areas of Guiyang City was determined by gas chromatography triple quadrupole mass spectrometer with selected ion mode.
    Result PAHs in soil of green belt mainly came from exogenous pollution. Six PAHs met the national construction land risk screening value standard, but the overall proportion of pollution is high. In the functional area of night market, a large amount of PAHs were produced by two main ways of barbecue and frying, which made the soil concentration in the adjacent green belt significantly higher than that in other functional areas. The results of characteristic ratio method showed that the combustion of biomass fuels (such as coal) occupied a certain proportion of the emission contribution sources of the residential area, and the main emission contribution source of the school functional area was the oil combustion exhaust emissions from motor vehicles. In terms of health risk assessment, skin contact was the main route of carcinogenic risk.
    Conclusion The proportion of the green belt contaminated soil in the main urban area of Guiyang City was relatively high, and the content of high molecular weight (4-6 rings) PAHs was higher than that low molecular weight (2-3 rings) PAHs. PAHs in green belt soil are potentially carcinogenic to children and adults. Therefore, corresponding measures should be taken to reduce pollution sources and pollution degree.

     

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