黄石市城区土壤重金属分布特征及来源解析

Source and Distribution Characteristics of Heavy Metals in Soil in Huangshi, China

  • 摘要:
    目的 研究资源枯竭型城市土壤重金属的污染风险与污染来源,保障黄石市区生态环境和人体健康。
    方法 自黄石市城区采集了49个表层土壤样品,测试了铬(Cr)、镍(Ni)、铅(Pb)、锌(Zn)、铜(Cu)5种重金属的含量,使用地累积指数法和潜在生态危害指数法对其进行污染评价,采用空间插值法分析金属含量空间分布特征,在主成分分析结果的基础上,利用正定矩阵因子模型(PMF)得到各类重金属的具体污染来源,及其对各重金属元素的贡献度。
    结果 研究区表层土壤中5种重金属含量的平均值均大于湖北省土壤背景值,其中Zn和Pb污染程度最高,超背景值率达到100%。污染评价结果显示,Pb是该区域污染最严重的重金属,而Ni是污染最轻的重金属元素,5种元素的潜在生态风险均表现出轻微生态风险,同时大部分样点的综合潜在生态危害指数小于150。
    结论 研究区重金属空间分布大致呈中间低、四周高的特点,整个研究区Cr和Ni的含量较低且分布均匀,仅部分样点含量偏高,Pb、Zn、Cu含量较高,有大面积的严重污染区域,其中高值区主要分布于人口密集、交通运输频繁区域,Zn和Pb的空间分布还具有一定相似性;土壤重金属污染源主要有三个,Cr、Ni主要为自然来源,Pb、Zn主要为交通来源,Cu主要为矿业来源。

     

    Abstract:
    Objective The purpose of this work is to analyze the pollution risks and sources of heavy metals in surface soil in Huangshi city, a resource-exhuasted city, and to support the protection of ecological environment and human health.
    Method 49 soil samples were collected and examined heavy metal content, which were Cr, Ni, Pb, Zn and Cu. Pollution levels were evaluated in line with Geo-accumulation index and potential ecological risk index, and the distribution patterns of heavy metals were depicted by spatial interpolation method. Furthermore, PCA (principal component analysis) and PMF (positive matrix factorization) were applied to analyze the sources of heavy metals and their contribution to each element.
    Result All the five heavy metals had their mean values higher than the soil background values in Hubei province, among which Zn and Pb were the most enriched elements. The potential ecological risk for each element and the comprehensive ecological risk for the overall area were similarly in the lower risk levels. Among five elements, Pb was classified the most polluted element whereas Ni the slightest polluted element. In addition, the spatial distribution of heavy metals was roughly characterized by lower values in the middle area and higher in the surroundings, specifically Cr and Ni were low and evenly distributed, while Pb, Zn and Cu had their higher values mainly distributed in areas with dense human activities.
    Conclusion The results showed that there were three main sources of soil heavy metal pollution, with Cr and Ni were mainly from natural sources, Pb and Zn mainly from transportation sources, and Cu mainly from mining sources.

     

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