河南省农田土壤重金属污染特征及来源解析

Characteristics of Heavy Metal Pollution and Source Analysis in Farmland Soil of Henan Province

  • 摘要:
    目的 本研究目的为理清河南省农田土壤重金属分布特征、污染现状及来源。
    方法 基于文献计量和实地检测的方法,共获得采样点位105个,以《土壤环境质量农用地土壤污染风险管控标准(试行)》(GB 15618—2018)中的相应的风险筛选值和管控值作为农田土壤重金属污染评价的依据,利用地累积指数法、潜在生态风险指数法和主成分分析法研究了河南农田土壤重金属的污染特征、分布特征、生态风险和主要来源。
    结果 豫西和豫北的铅(Pb)平均含量大于筛选值,豫东、豫南、豫西和豫北的隔(Cd)平均含量大于筛选值,铜(Cu)、锌(Zn)、砷(As)、镍(Ni)和铬(Cr)的平均含量均低于筛选值,但除Ni外,均大于河南省土壤背景值。河南农田土壤重金属Pb、Cu、Cd、Zn、As、Ni和Cr的超标率分别为21.51%、11.84%、43.82%、6.67%、8.06%、3.85%和6.17%,其中济源、新乡、焦作等地需要重点关注。从地累积指数(Igeo)来看,Cu、Zn、As、Ni和Cr的平均值属于无污染程度,Cd和Pb的Igeo呈现的污染程度最高,Igeo均值分别为1.65(中污染)和0.39(轻-中污染)。重金属中,Cd具有极强的潜在生态风险,不同区域中,Cd在豫北的潜在生态风险等级为极强,在豫西的潜在生态风险等级为强风险,需要重点关注。河南省不同区域重金属来源不同,豫东地区为交通源和农业-自然混合源,豫南地区为自然源、农业源和工业源,豫西地区为农业-自然混合源和工业源,豫北地区为工业源和农业源,豫中地区为工业-自然混合源和交通源。
    结论 河南农田重金属污染整体可控,但重金属来源较为复杂,且豫西和豫北地区污染程度大于其他区域,尤其是Cd和Pb的污染需要长期重点跟踪研究。针对河南农田土壤污染现状,建议坚持源头管理,优化产业布局,调整种植结构,同时加强基础研究的政策和资金倾斜,以期为河南省农田重金属污染防控提供理论支撑,加快实现农业绿色可持续发展。

     

    Abstract:
    Objective The aim of this study was to elucidate the distribution characteristics, pollution levels, and sources of heavy metals in farmland soils throughout Henan province.
    Method Based on bibliometric and field testing methods, a total of 105 sampling points were obtained, corresponding risk screening and control values in the 《Soil Environmental Quality Agricultural Land Soil Pollution Risk Control Standard (Trial)》(GB 15618−2018) as the basis for evaluating heavy metal pollution in agricultural soil. Based on a large amount of literature data, the land accumulation index method, potential ecological risk index method and principal component analysis method were used to study the pollution characteristics, distribution characteristics, ecological risks and main sources of heavy metals in farmland soil in Henan province.
    Result The average contents of Pb in western and northern Henan were higher than those of the screening value, while the average contents of Cd in eastern, southern, western, and northern Henan were higher than those of the screening value. The average contents of Cu, Zn, As, Ni, and Cr were all lower than the screening value, except for Ni. They were all higher than the soil background value in Henan Province. The exceeding rates of heavy metals of Pb, Cu, Cd, Zn, As, Ni, and Cr in farmland soil in Henan province are 21.51%, 11.84%, 43.82%, 6.67%, 8.06%, 3.85% and 6.17%, respectively. Key areas such as Jiyuan, Xinxiang, and Jiaozuo needed to be given special attention. From the perspective of geo-accumulation index(Igeo), the average values of Cu, Zn, As, Ni, and Cr belonged to non-pollution, while Cd and Pb had the highest degree of land accumulation pollution, with Igeo mean values of 1.65 (medium pollution) and 0.39 (light to medium pollution), respectively. Of all the heavy metals, Cd had extremely strong potential ecological risks. In different regions, the potential ecological risk level in northern Henan was extremely strong, while the potential ecological risk level in western Henan was strong and required special attention. Heavy metal sources varied across different regions of Henan province. The eastern region of Henan province was dominated by traffic and agricultural-natural mixed sources. The southern Henan region was characterized by natural, agricultural, and industrial sources. The western Henan region was primarily agricultural-natural mixed and industrial sources. The northern Henan region was mainly industrial and agricultural sources. The central Henan region was influenced by industrial-natural mixed and traffic sources.
    Conclusion Heavy metal pollution in farmland in Henan is generally controllable, but the sources of heavy metals are relatively complex, and the pollution level in the western and northern regions of Henan is greater than that in other regions, especially the pollution of Cd and Pb, which requires long-term and focused tracking and research. In response to the current situation of soil pollution in farmland in Henan province. It is recommended to adhere to source management, optimize industrial layout, adjust planting structure, and strengthen policy funding for basic research, in order to provide theoretical support for the prevention and control of heavy metal pollution in farmland in Henan province, and will expedite the achievement of environmentally friendly and sustainable agricultural development.

     

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